Quantum chemical investigations of the mechanisms of carboand heterocycles assemblies based on acetylenes reactions in superbasic media

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Abstract

The chemistry of acetylenes has received significant development in the context of the use of superbasic media in organic synthesis. The study of reaction mechanisms requires the use of a complex of chemical, physicochemical, and theoretical methods. This review presents the results of recent quantum-chemical studies on mechanisms of assemblies based on the reactions of acetylene and its derivatives occurring in superbasic media and yielding in the formation of complex deeply functionalized molecular structures, which are being developed at the Irkutsk Institute of Chemistry named after A.E. Favorsky SB RAS.

About the authors

N. M Vitkovskaya

Irkutsk State University

Email: vita@cc.isu.ru

V. B Orel

Irkutsk State University

V. B Kobychev

Irkutsk State University

A. S Bobkov

Irkutsk State University

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