Direct cross-dehydrogenative С–N-coupling of phenanthridine with 1H-benzotriazole

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Abstract

An approach was developed for the direct C( sp 2)-H-functionalization of phenanthridine with a 1 H -benzotriazole residue, carried out in the presence of Selectfluor® reagent and leading to the formation of a C( sp 2)-N bond. The procedure described in this communication makes it possible to obtain α-(1 H -benzotriazol-1-yl)phenanthridine, which is a valuable synthon for further chemical transformations, in one step and using commercially available substrates and reagents.

About the authors

A. A Akulov

Ural Federal University named after the first President of Russia B.N. Yeltsin

A. A Pershin

Ural Federal University named after the first President of Russia B.N. Yeltsin

D. S Kopchuk

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

M. V Varaksin

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

G. V Zyryanov

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

Email: gvzyryanov@gmail.com

O. N Chupakhin

Ural Federal University named after the first President of Russia B.N. Yeltsin;I.Ya. Postovsky Institute of Organic Synthesis, Russian Academy of Sciences, Ural Branch of the Russian Academy of Sciences

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