Synthesis of new fluorene-containing 9-azabicyclo[4.2.1]nona-2,4,7-trienes [6π+2π]-cycloaddition of alkynes to N-carbofluorenylmethoxyazepine

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Abstract

Catalytic [6π+2π]-cycloaddition of terminal alkynes to N -carbofluorenylmethoxyazepine under the action of a three-component catalytic system Co(acac)2(dppe)/Zn/ZnI2 was performed for the first time to obtain previously undescribed and promising 9-azabicyclo[4.2.1]nona-2,4,7-trienes (in 79-92% yields) containing a fluorene substituent.

About the authors

G. N Kadikova

Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences

Email: kad.gulnara@gmail.com

V. A D'yakonov

N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences

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