Photoinitiated by red light (625 nm) iodosulfonylation of internal alkynes to synthesize β-iodovinylsulfones

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Abstract

Synthesis of β-iodovinyl sulfones was performed out by direct bifunctionalization of internal alkynes using an economical LED light source with a maximum emission wavelength of 625 nm. The products were obtained in high yields (68 to 99%) using equivalent amounts of reagents. The reaction of arylsulfonyl iodides with internal alkynes proceeds by a radical mechanism and is a regioselective method for the synthesis of β-iodovinyl sulfones.

About the authors

V. A. Abramov

Topchiev Institiute of Petrochemical Synthesis, Russian Academy of Sciences

M. A. Topchiy

Topchiev Institiute of Petrochemical Synthesis, Russian Academy of Sciences

A. S. Malysheva

Topchiev Institiute of Petrochemical Synthesis, Russian Academy of Sciences

I. P. Beletskaya

Topchiev Institiute of Petrochemical Synthesis, Russian Academy of Sciences

A. F. Asachenko

Topchiev Institiute of Petrochemical Synthesis, Russian Academy of Sciences

Email: aasachenko@ips.ac.ru

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