Interaction of Methylenecycloalkanes with BF3·THF Catalyzed by 2TiCl2

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Abstract

The Cp2TiCl2-catalyzed interaction of methylenecycloalkanes with BF3·THF in tetrahydrofuran was carried out for the first time with the formation of target 1-fluoro-1-boraspirocarbocycles and also isomerization products of a starting monomer (1-methylcycloalk-1-enes). The structure of reaction products was elucidated using one(1H, 13C Dept, 11B, 19F) and two-dimensional (COSY, HSQC, HMBC) NMR spectroscopy, mass spectrometry combined with quantum-chemical calculations of 13C NMR chemical shifts.

About the authors

L. I. Tulyabaeva

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

Email: khusainova_ink@mail.ru

R. R. Salakhutdinov

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

A. R. Tulyabaev

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

T. V. Tyumkina

Institute of Petrochemistry and Catalysis, Ufa Federal Research Centre, Russian Academy of Sciences

M. F. Abdullin

Ufa Institute of Chemistry, Ufa Federal Research Centre, Russian Academy of Sciences

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